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Compare two papers, two materials, a normal-gravity flame with a microgravity one, and the extinguishing options studied for spacecraft.

Two papers

30th ASGSR Conference

Combustion of Solids in Microgravity: Results from the BASS-II Experiment

Year
2014
Evidence
Real microgravity
Platform
ISS
Fuel
PMMA, SIBAL
O₂
13.6–21 %
Pressure
1 atm
Airflow
0–55 cm/s
Findings
38 quoted statements
Key finding
PMMA burned steadily at 13.6 % O₂ in orbit while the 1g limit is 16 % — a negative oxygen margin of safety of 2.4 %.
53rd ICES, Louisville

Preliminary Results from the Saffire VI Experiment

Year
2024
Evidence
Real microgravity
Platform
Cygnus
Fuel
SIBAL, Cotton, PMMA
O₂
28.8–31 %
Pressure
54.1–55.2 kPa
Airflow
20 cm/s
Findings
27 quoted statements
Key finding
1.5–3.2 kW fires in a 17–19 m³ cabin: CO and CO₂ passed crew limits, while smoke was detected only at 981 s — after most toxic gas was released.

Two materials

Flammability facts stated in the sources.

PMMA (acrylic)

O₂ limit, 1g
16 % (¼" rod blowoff)
O₂ limit, µg
13.6 % (steady spread)
Margin of safety
−2.4 % O₂ (burns more easily in µg)
Limiting flow Vlim
0.5 cm/s at 23.6 % O₂
Saffire outcome
VI-3/VI-4: CO and CO₂ above crew limits; burned up to 1200 s

Nomex HT90-40

O₂ limit, 1g
≈ 24–25 % O₂
In µg (ISS)
Did not burn at 21–22 % O₂, ~15 cm/s
Saffire outcome
Not ignited by a 460 W PMMA pilot flame
Note
Nomex-III (a different grade) did burn on ISS

Normal vs microgravity flame

Same PMMA, same 21 % O₂. Left: Earth. Right: ISS with a gentle 3 cm/s airflow.

Normal gravity
Microgravity
AspectNormal gravityMicrogravitySource
ShapeTeardrop, tallSpherical / hemispherical, shorter and wider
ColourBright yellow (soot)Dim blue, extended blue zone
BaseConcave base, extended soot zoneConvex base
BehaviourGrowing, flickering, pulsating spreadSteady size and spread
Distance from fuelClose to surfaceFarther from surface, dimmer, less soot
Oxygen supplyBuoyant convectionDiffusion + ventilation only

Extinguishing options

What each method achieved in the experiments, with the evidence behind it.

Vent / flow shutoff

Effective for thin fuels in air

Mir: extinction 5–20 s after shutoff; <13 s in µg vs 55 s in 1g. Saffire I: immediate.

Caveat: Thick or hot fuels and enriched O₂ can survive no-flow periods.

Evidence (3)
“It has been demonstrated that at flow shutoff the extinction in microgravity occurs in 5 to 20 s, which is significantly lower than the extinction time obtained during the ground testing.”
“The space experiment indicated that the fire extinguishes faster in microgravity (1:1< 13 sec) at flow shutoff than in normal gravity 0:1 = 55 sec).”
“Extinguishment [8]. Extinguishment of bubbling polymers cannot be assumed to occur rapidly in quiescent conditions. Flame shrank during the reduced flow interval of 65 seconds but survived the 15 second no-flow interval. Flame extinguished below the sample for 6.4 seconds but reignited. Plot axis: Incident Flux (mW/cm^2).”

Helium

Promising (drop-tower only)

More effective than CO₂ per mole at µg and ~11× per mass; no physiological activity; less bubble risk on depressurization.

Caveat: Not yet tested on long-duration platforms.

Evidence (2)
“First, helium is more effective than CO2 on a mole basis (thus pressure times storage volume basis) at µg, meaning that the size and weight of storage bottles would be smaller for the same fire-fighting capability.”
“Third; helium has no physiological activity, unlike CO2 that affects human respiration.”

CO₂

Mixed — ISS standard, but weaker in µg

Raises the oxygen needed to burn (21 → ~35 % as diluent), but in µg can radiate heat to fuel; no clear extinction boundary in 142 points.

Caveat: Affects crew respiration; can cause unsteady spread.

Evidence (3)
“Results show, first, that the substitution of carbon dioxide as the atmospheric diluent for nitrogen greatly diminishes the flammable range; the limiting oxygen concentration for combustion is increased from 21 vol% to near 35 %.”
“CO2 may not be as effective as an extinguishing agent at µg as it is at earth gravity in some conditions because of the differences in spread mechanisms between the two cases.”
“On this plot, there is no discernable boundary between flames that were extinguished by suppressant and those that were not.”

Nitrogen

Weak on hot thick fuels

A 500 cc/min N₂ jet weakened but did not extinguish a PMMA flame; flushing with N₂ was used to end ground tests.

Caveat: Warm solids keep re-igniting.

Evidence (2)
“Nitrogen flow of 500 cc/min weakens but does not extinguish the flame”
“The flames were extinguished by flushing the system with nitrogen after they had spread over the entire sample region.”

Venting to vacuum

Works, with a flare-up

Skylab: vacuum extinguishes when O₂ drops enough; µg flames are much more pressure-sensitive (PLF 78 % vs 13 %).

Caveat: Induced flow briefly intensifies the flame.

Evidence (2)
“Extinguishment by vacuum is effective, and the flame is extinguished when the available oxygen decreases sufficiently.”
“The observation of venting in Skylab indicated that the depressurization-induced flow causes a flame to flare up, and presumably spread faster, before it succumbs to the reduced total-pressure environment.”

Water

Possible if controlled

Skylab showed water extinguishment is possible with controlled, adequate application.

Caveat: Very little data.

Evidence (1)
“In addition to the flame-spread data, the Skylab experiments provided two observations of fire extinguishment that are still of interest for current applications: Extinguishment by water is possible, provided the application is controlled and adequate.”
Verdicts are one-line summaries of the quoted results, not measured scores — open the evidence before relying on them.